[Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate

نویسندگان

  • Maksym Seredyuk
  • Vadim A. Pavlenko
  • Elzbieta Gumienna-Kontecka
  • Turganbay S. Iskenderov
چکیده

In the title binuclear complex, [Cu2(NO3)3(C18H16N6Se)(H2O)3]NO3·H2O, the Cu(II) ions are penta-coordinated in a tetra-gonal-pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol-ecule and a nitrate O atom, whereas the apical positions are occupied by a water mol-ecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C-Se-C plane. Numerous inter-molecular O-H⋯O and N-H⋯O hydrogen bonds between the coordinating and lattice water mol-ecules, nitrate anions and pyrazole groups are observed. π-π stacking inter-actions between the pyridine rings [averaged centroid-centroid distance = 3.652 (5) Å] are also present. The lattice water molecule is equally disordered over two sets of sites.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

[Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate

In the binuclear title complex, [Cu2(ClO4)1.5(NO3)1.5(C18H16N6Se)(H2O)5]NO3·H2O, both Cu(II) ions are hexa-coordinated by O and N atoms, thus forming axially elongated CuO4N2 octa-hedra. The equatorial plane of each octa-hedron is formed by one chelating pyrazole-pyridine fragment of the organic ligand and two water mol-ecules. The axial positions in one octa-hedron are occupied by a water mol-...

متن کامل

Aqua­bis­(1-methyl-1H-imidazole-κN 3)bis­(nitrato-κO)copper(II)

The title complex mol-ecule, [Cu(NO(3))(2)(C(4)H(6)N(2))(2)(H(2)O)], has crystallographically imposed twofold symmetry. The Cu(II) atom displays a distorted square-pyramidal CuN(2)O(3) coordination geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds between the coordinated water mol-ecule and the nitrate anions form chains parallel to the c axis.

متن کامل

Di-μ-methano­lato-κ4 O:O-bis­[bis­(3-methyl-5-phenyl-1H-pyrazole-κN 2)(nitrato-κO)copper(II)]

Copper nitrate in methanol solution cleaves the N-C(methanol) bond when reacted with 3-methyl-5-phenyl-pyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methano-late ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate...

متن کامل

Bis(nitrato-κO)bis­[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN 3)-2-imidazoline-1-oxyl 3-oxide-κO]nickel(II)

In the centrosymmetric mononuclear title complex, [Ni(NO(3))(2)(C(11)H(17)N(4)O(2))(2)], the Ni(II) atom displays a distorted octa-hedral coordination geometry and is six-coordinated by two N,O-bidentate nitronyl nitroxide radical ligands and two monodentate nitrate anions.

متن کامل

catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ2 N 4:N 4′]]

In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O at...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012